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New versatile C5 buildig blocks from ethylene and tetrachlorocyclopropene
Authors:Thomas Liese  Gisela Splettstäber  Armin de Meijere
Abstract:The perchlorovinylcarbene adducts of ethylene and propylene served as precursors toa wide spectrum of 1’-substituted cycllorpropylacetylenes 4, 8 and 9, which are versatile polyfunctional molecules. E.g., the acetylenic ester 4c underwent cycloaddition to1,3-dienes giving otherwise unaccessible compounds.
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