A method for the systematic resolution of unbranched α-acetoxyalkyl- and aralkylaldehydes: synthesis of <span class="math"><math><mtext>11R</mtext></math></span> and <span class="math"><math><mtext>11S</mtext></math></span>-hete期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

A method for the systematic resolution of unbranched α-acetoxyalkyl- and aralkylaldehydes: synthesis of $11R$ and $11S$ -hete

Authors:	George Just Corinne Luthe Pierre Potvin

Affiliation:	Department of Chemistry, McGill University Montreal, Canada H3A 2K6

Abstract:	It is shown that oxazolidines derived from racemic unbranched α-acetoxyaldehydes and ?-ephedrine have predictable chromatographic mobilities, with the R-isomer always having a higher R_f-value. This resolution has been used to prepare $11R$ and $11S$ -HETE.

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