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Uncatalyzed insertion reaction of isocyanides into a carbon-sulfur bond |
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| Authors: | G. Morel E. Marchand K.H. Nguyem Thi A. Foucaud |
| Affiliation: | Groupe de Physicochimie Structurale associéau C.N.R.S., Universitéde Rennes, Campus de Beaulie, 35042 Rennes, France |
| Abstract: | Tert-butylisocyanide and tert-octylisocyanide insert into the carbone-sulfur bond of activated sulfides 2 yielding thioimidates 5 which rearrange to enamines 6. |
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