Biomimetic entry to acyclic terpene synthesis a novel rearrangement of allyl ether catalyzed by organoaluminium reagents |
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Authors: | Yoshihiro Yamamura Kensuke Umeyama Keiji Maruoka Hisashi Yamamoto |
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Institution: | Department of Applied Chemistry, Nagoya University Chikusa, Nagoya 464 Japan |
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Abstract: | The intramolecular prenyltransfer reaction is accomplished by the rearrangement of allyl ethers with (2,6-di--butyl-4-methylphenoxy)methylaluminum trifluoromethanesulfonate. The present method provides a simple and highly efficient synthesis of lavandulol. |
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