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Isolation and structures of trans-laurencenyne,a possible precursor of the C15 halogenated cyclic ethers,and trans-neolaurencenyne from laurencia okamurai
Authors:Hideo Kigoshi  Yoshikazu Shizuri  Haruki Niwa  Hiyoyuki Yamada
Institution:Department of Chemistry, Faculty of Science, Nagoya University, Chikusa, Nagoya 464 Japan
Abstract:Isolation and structural elucidation of two new acetylenic polyenes, trans-laurencenyne 1 and trans-neolaurencenyne 2 from the marine red alga Laurencia okamurai were carried out, the former compound 1 very recently being proposed to be a biosynthetic precursor of the C15 halogenated cyclic ethers, 7 and 8.
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