Aluminum-chloride catalyzed reaction of allylic sulfides with methyl propiolate: A novel addition reaction via an ionic [3.3] sigmatropic rearrangement |
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| Authors: | Kenji Hayakawa Yoshimasa Kamikawaji Ken Kanematsu |
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| Affiliation: | Institute of Synthetic Organic Chemistry, Faculty of Pharmaceutical Sciences, Kyushu University, Maidashi, Higashi-ku, Fukuoka 812, Japan |
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| Abstract: | The aluminum-chloride catalyzed reaction of allylic sulfides with methyl propiolate resulted in the clean formation of novel 1:1 adducts via ionic [3.3] sigmatropic rearrangements. |
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