Secondary tritium isotope effects,a useful mechanistic probe for the study of acetoxyl participation and transfer |
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| Authors: | Saul Wolfe Peter G.C. Campbell |
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| Affiliation: | Department of Chemistry, Queen''s University, Kingston, Ontario, Canada K7L 3N6;Institut national de la recherche scientifique (INRS-EAU), Université du Québec, Case postale 7500, Sainte-Foy, Québec, Canada G1V 4C7 |
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| Abstract: | Tritium labelling on the acetoxyl methyl group has been used to probe the mode of incorporation of acetate into cinnamyl acetate in the solvolyes of cinnamyl chloride and cinnamylmercuric acetate, and in the allylic oxidation of allylbenzene with mercuric acetate. |
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