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Two new angular methyl dioxygenated D:A-fried-oleananes
Authors:Gamini Weeratunga  Vijaya Kumar  M Uvais S Sultanbawa
Institution:Departement of Chemistry, University of Paradeniya, Paradeniya, Sri Lanka
Abstract:Two new trioxygenated D:A-friedo-oleananes from Elaeodendron glaucum have been shown to be the angular methyl dioxygenated 25,28-dihydroxy-D:A-friedo-oleanan-3-one(1) and 3,28-dioxo-D:A-friedo-oleanan-25-ol(2) by interconversion and deoxygenation of the alcohol(2) using Lithium-ethyle diamine reduction coupled with spectroscopic methods.
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