A mild method for the conversion of proipiolic esters to β-keto esters. application to the formal total synthesis of (±)-thienamycin |
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| Authors: | Masakatsu Shibasaki Atsushi Nishida Shiro Ikegami |
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| Affiliation: | Faculty of Pharmaceutical Sciences, Teikyo University, Sagamiko, Kanagawa 199-01, Japan |
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| Abstract: | An extremely mild method for the transformation of propiolic esters to β-keto esters via thiol addition is reported, including its successful application to the synthesis of (±)-thienamycin. |
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