The synthesis of N-substituted ketimines from oxazirdines |
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Authors: | Derek R Boyd Kenneth M McCombe Narain D Sharma |
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Institution: | Department of Chemistry, Queen''s University, Belfast BT9 5AG Northern Ireland |
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Abstract: | N-Unsubstituted diaryl, alkyl aryl and dialkyl ketimines are prepared in good yield at ambient temperature by the reaction of KOBut on oxaziridines having an α-hydrogen atom on the N-alkyl substituent; the mechanism and stereochemistry of the reaction are discussed. |
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