The role of trimethylsilyl group in highly stereoselective eposidation of allylic alcohols |
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| Authors: | Hiroki Tomioka Toshifumi Suzuki Koichiro Oshima Hitosi Nozaki |
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| Institution: | Department of Industrial Chemistry, FAculty of Engineering Kyoto University, Yoshida, Kyoto 606, Japan |
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| Abstract: | The epoxidation of allylic alcohols carrying Me3Si group on the double bonds with VO(acac)2-tBuOOH or MCPBA provides erythro or threo epoxy alcohols, respectively with high stereoselectivity. |
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