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Regiocontrolled 1,2-, 1,4-, and 1,6-additions of organometallics to unsaturated thioamides |
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| Authors: | Y Tamaru T Harada S Nishi Z Yoshida |
| Institution: | Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University, Yoshida, Kyoto 606, Japan |
| Abstract: | 1,4-Addition of allyllithiums to α,β-unsaturated thioamides and 1,4-(kinetic) and 1,6-(thermodynamic)regiocontrolled additions of lithium enolates to thiosorbamide are reported. |
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