The reaction of triethylamine with bromine. An evaluation of the formation constant of the transient 1:1 complex and a study of its conversion into products. |
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| Authors: | G Bellucci G Berti R Bianchini L Orsini |
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| Institution: | Istituto di Chimica Organica, Facoltá de Farmacia, via Bonanno 6, 56100 Pisa, Italy. |
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| Abstract: | Triethylamine and bromine in 1,2-dichloroethane give a non isolable 1:1 charge transfer complex with Kf>107 M?1, which undergoes a fast intramolecular oxidation to N,N-diethylethyldeneiminium bromide and hydrogen bromide. |
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