Unstable capillary flow of reinforced polymer melts

The injection capillary flow of various unfilled and glass fibre or calcium carbonate filled polypropylene and nylon 6.6 melts is studied using either a single capillary of five capillaries in series, separated by small reservoirs. Only unfilled nylon 6.6 yields instability during flow through a single capillary due to mechanochemical degradation in the capillary at extremely high shear rates above 5 × 10⁵ s^?1. It is found that only short glass fibre reinforced polypropylene yields high frequency oscillations in the reservoir pressure and extrudate diameter and has discontinuity in the flow curve when the apparent shear rate is above 4 × 10⁵ s^?1 and the flow is through multiple capillaries. Further increase in the shear rate restores the stable flow. The intensity of the oscillations and the range of shear rate during which unstable flow occurs are increased with increasing melt temperature. The mechanism of this unstable flow is investigated by studying fibre orientation at the capillary entrance and exit using mouldings simulating capillary entry-exit flows.