Grafting Titanocene on Hydrophilic Amorphous Silica:Synthesis of an Effective Catalyst for Olefin Epoxidation |
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Authors: | Sam-Hun Yun Jie Bu Hyun-Ku Rhee |
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Affiliation: | (1) School of Chemical Engineering and Institute of Chemical Processes, Seoul National University, Kwanak-ku, Seoul, 151-742, Korea |
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Abstract: | Ti/silica catalysts were prepared by grafting titanocene dichloride (Cp2TiCl2) on hydrophilic amorphous silica with different Ti contents under mild conditions. The results of FT-IR, UV-vis and XPS analyses proved that titanium was successfully grafted in the form of Ti(IV) on amorphous silica and the maximum content of Ti grafted was found to be ca. 3 wt.%. When cyclohexene epoxidation with TBHP was carried out over these synthesized catalysts, both the activity and the selectivity to epoxide increased with the amount of Ti grafted. This amorphous Ti/silica catalyst showed a higher activity and a higher selectivity to epoxide than Ti-containing molecular sieves, Ti-MCM-41 and Ti-beta, with nearly the same Ti content. With Ti content larger than 3 wt.%, however, anatase phase (TiO2) was formed to give a lower activity and selectivity to epoxide. |
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Keywords: | Titanocene grafting silica titanium cyclohexene epoxidation |
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