Use of X-ray photoelectron and Mössbauer spectroscopies in the study of iron pentacyanide complexes |
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| Authors: | K.B. Yatsimirskii V.V. Nemoshkalenko Yu.P. Nazarenko V.G. Aleshin V.V. Zhilinskaya N.A. Tomashevsky |
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| Affiliation: | 1. Institute of Metal Physics, Academy of Sciences of the Ukrainian S.S.R., Kiev-142, Vernadskogo 36 U.S.S.R. |
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| Abstract: | A number of iron pentacyanide complexes of the Naitn [Fe(CN)5X] type have been synthesized. The compounds have been examined by X-ray photoelectron (ESCA) and Mössbauer spectroscopies. The influence of the nature of ligand X upon the properties of iron- (II) pentacyanide complexes has been studied. The donor properties of dinitrogen as a ligand have been compared with those of other nitrogen-containing ligands. A correlation has been established between the ESCA and Mössbauer data. |
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