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Facile Synthesis,Characterization, and Fluorescence Studies of Novel Porphyrin Appended Thiazoles
Authors:Bhupendra Mishra  K P Chandra Shekar  Anil Kumar  S Phukan  S Mitra  Dalip Kumar
Institution:1. Chemistry Group, Birla Institute of Technology and Science, , Pilani, 333 031 India;2. Department of Chemistry, North‐Eastern Hill University, , Shillong, 793 022 India
Abstract:A facile and high yielding synthesis of porphyrin appended thiazoles 5 from the reaction of 5‐(4‐thiocarboxamidophenyl)‐10,15,20‐triphenylporphyrin with α‐bromo ketones has been described. The fluorescence studies of synthesized porphyrin appended thiazoles 5 in chloroform indicate that porphyrin π system is not greatly perturbed by substitution of a thiazole moiety at meso‐phenyl ring even in the excited state.
Keywords:Porphyrin  Thiazoles  Porphyrin appended thiazole  Fluorescence
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