Facile Synthesis,Characterization, and Fluorescence Studies of Novel Porphyrin Appended Thiazoles |
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Authors: | Bhupendra Mishra K P Chandra Shekar Anil Kumar S Phukan S Mitra Dalip Kumar |
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Institution: | 1. Chemistry Group, Birla Institute of Technology and Science, , Pilani, 333 031 India;2. Department of Chemistry, North‐Eastern Hill University, , Shillong, 793 022 India |
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Abstract: | A facile and high yielding synthesis of porphyrin appended thiazoles 5 from the reaction of 5‐(4‐thiocarboxamidophenyl)‐10,15,20‐triphenylporphyrin with α‐bromo ketones has been described. The fluorescence studies of synthesized porphyrin appended thiazoles 5 in chloroform indicate that porphyrin π system is not greatly perturbed by substitution of a thiazole moiety at meso‐phenyl ring even in the excited state. |
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Keywords: | Porphyrin Thiazoles Porphyrin appended thiazole Fluorescence |
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