KI‐VO(acac)2‐H2O2‐AcOH,A New Iodinating System for Selective Iodination at C‐5 Position of Activated Pyrimidinediones: A Combined Experimental and Density Functional Study |
| |
| Authors: | Lakhinath Saikia Dhrubajyoti Talukdar Ramesh C Deka Ashim J Thakur |
| |
| Institution: | Department of Chemical Sciences, Tezpur University, , Tezpur, 784 028 Assam, India |
| |
| Abstract: | KI‐VO(acac)2‐H2O2 in aqueous ethanolic medium with acetic acid as additive has been found to iodinate pyrimidinediones and aromatic amines. The methodology is mild, efficient, and environmentally benign. Density functional theory‐based reactivity parameters support the experimentally observed reactivity of pyrimidinedione derivatives. |
| |
| Keywords: | |
|
|
