| 二苯基烷基膦-硼烷的合成 |
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| 引用本文： | 杨文谦,黄天宝,刘玲飞,何良年,张景龄.二苯基烷基膦-硼烷的合成[J].高等学校化学学报,1996,17(7):1083. |
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| 作者姓名： | 杨文谦 黄天宝 刘玲飞 何良年 张景龄 |
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| 作者单位： | 华中师范大学有机合成研究所, 武汉 430070 |
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| 摘 要： | 二苯基烷基膦－硼烷的合成杨文谦，黄天宝，刘玲飞，何良年，张景龄（华中师范大学有机合成研究所，武汉，４３００７０）关键词二苯基烷基膦－硼烷，三苯基膦－硼烷，合成，烷基化膦－硼烷化合物（Ｒ３Ｐ→ＢＨ３），特别是连接不同取代基的膦－硼烷（Ｒ１Ｒ２Ｒ３Ｐ→Ｂ...
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| 关 键 词： | 二苯基烷基膦-硼烷 三苯基膦-硼烷 合成 烷基化 |
| 收稿时间： | 1995-07-20 |
Synthesis of Diphenylalkylphosphine-boranes |
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| YANG Wen-Qian, HUANG Tian-Bao,LIU Ling-Fei,HE Liang-Nian,ZHANG Jing-Ling.Synthesis of Diphenylalkylphosphine-boranes[J].Chemical Research In Chinese Universities,1996,17(7):1083. |
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| Authors: | YANG Wen-Qian HUANG Tian-Bao LIU Ling-Fei HE Liang-Nian ZHANG Jing-Ling |
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| Institution: | Institute of Organic Synthesis, Central China Normal University, Wuhan 430070 |
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| Abstract: | Anew and facile method for the preparation of diphenylalkylphosphine-boranes 2 was described.Treatment of the available triphenyl phosphine-borane 1 with Na under room temperature,then with propriate alkyl halides below-10℃ afforded seven 2 in good yield,and they were characterized by IR,31P NMR,1H NMRand microanalysis,partially by MS. |
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| Keywords: | Diphenylalkylphosphine-borane Triphenylphosphine-borane Preparation Alkylation |
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