Ethylene sulfate as film formation additive to improve the compatibility of graphite electrode for lithium-ion battery |
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Authors: | Xuecheng Li Zhoulan Yin Xinhai Li Chao Wang |
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Institution: | 1. College of Chemistry and Chemical Engineering, Central South University, Changsha, Hunan, 410083, China 3. School of metallurgy and Enviroment, Central South University, Changsha, Hunan, 410083, China 2. Jiangxi Youli New Material Co., Ltd, Pingxiang, Jiangxi, 337000, China
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Abstract: | Ethylene sulfate (DTD) is investigated as a novel film formation electrolyte additive for graphite anode material in lithium-ion battery. The CV results reveal that DTD is reduced prior to ethylene carbonate (EC) at the interface between graphite and electrolyte, while it cannot prevent the sustained reduction of propylene carbonate (PC) when the amount of DTD is lesser than 3 wt% in the PC-based electrolyte. XPS analyses demonstrate that the reduction products of DTD, Li2SO3, and ROSO2Li are formed at the surface of graphite in the EC-based electrolyte, which is beneficial to lower the interfacial resistance as suggested by the EIS results. In addition, SEM images show a smoother and homogeneous surface film at the surface of graphite when DTD is incorporated into the electrolyte. Consequently, the Li/graphite half cells cycled in EC-based electrolyte containing DTD exhibit higher specific capacity and improved cycling capability than that without DTD. |
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