Properties of two polymerisable surfactants aqueous solutions: dodecylethylmethacrylatedimethylammonium bromide and hexadecylethylmethacrylatedimethylammonium bromide. II. Partial molar volume and micelle hydration
(1) Departamento de Ingeniería Química, CUCEI, Universidad de Guadalajara, 44430 Guadalajara, Jalisco, México;(2) Departamento de Química, Universidad Nacional del Sur, 8000 Bahía Blanca, Buenos Aires, Argentina
Abstract:
The partial molar volume and hydration number of two micellised polymerisable surfactants (dodecylethylmethacrylatedimethylammonium bromide (C12PS) and hexadecylethylmethacrylatedimethylammonium bromide (C16PS)) were determined. Results support marginally the annular conformation of the polar head group (N+(CH3)2-CH2-CH2-O-CO-C(CH3)(=CH2)) proposed in the literature.