Abstract: | Tetrafluoroaurates(III) of Lanthanides MFAuF4]2 (M = Tm, Yb, Lu) . Tetrafluoroaurates(III) MFAuF4]2 with M = Tm, Yb, Lu, all yellow, have been prepared for the first time. From single crystal data they crystallize orthorhombic, space group Pbcn-D (No. 60) with M = Tm: a = 1 102.92(8) pm, b = 904.38(8) pm, c = 2 164.46(23) pm; M = Yb: a = 1 100.98(12) pm, b = 902.23(8) pm, c = 2 157.36(23) pm; M = Lu: a = 1 099.28(18) pm, b = 900.70(15) pm, c = 2 151.50(46) pm. |