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Eisen- und Mangankomplexe mit sauerstoff-, schwefel- und methylen-verbrückten Distibanen und mit Chlorodiphenylstiban als Liganden |
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| Authors: | N. Graf M. Wieber |
| Abstract: | Complexes of Iron and Manganese with Oxygen-, Sulfur-, and Methylene-bridged Distibines and with Chlorodiphenylstibine as Ligands The photochemical reaction of CO3Fe[P(OPh)3]2 and of MeCpMn(CO)3 with the stibines Ph2SbCl and (Ph2Sb)2X (X = O, S and CH2) yields mononuclear complexes (CO)2[P(OPh)3]2FeL and °Cp(CO)2MnL (L = Ph2SbCl, (Ph2Sb)2X) and the stibine bridged binuclear complexes °CO)2[P(OPh)3]2Fe{(Ph2Sb)2X}Fe(CO)2[P(OPh)3]2 and °Cp(CO)2Mn{(Ph2Sb)2X}Mn(CO)2MeCp. |
| Keywords: | Dicarbonylbis(triphenylphosphite)(stibine)iron complexes Bis[dicarbonylbis(triphenylphosphite)iron](stibine) complexes Dicarbonyl(η 5-methylcyclopentadienyl)(stibine)manganese complexes Bis[dicarbonyl(η 5-methylcyclopentadienyl)manganese](stibine) complexes |