Determination of carbonyl compounds via polarography of their semicarbazone derivatives |
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Authors: | B Fleet |
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Institution: | Department of Chemistry, Imperial College, London S.W. 7 Great Britain |
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Abstract: | The polarographic behaviour of a range of aldehyde and ketone semi-carbazones has been studied and a method for the determination of carbonyl compounds developed. The carbonyl compound is added to an acetate buffer containing 0.1 M semicarbazide hydrochloride and 50% ethanol and the polarographic reduction wave of the semicarbazone derivative measured. The similar values of the diffusion current constant I for all compounds studied indicate the applicability of this method to functional group analysis. |
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