Amperometric titration of copper in brass

A direct amperometric titration of copper is described; o-(p-tolylsulfonamido) aniline serves as titrant. The optimum conditions are discussed and the method is applied to the analysis of copper in brass alloys.

t001. IV. Analysis of various samples in which copper was determined (Values given as percentages)

Constituents	Thorn Smith # 30	Thorn Smith # 54	NBS # 37E	NBS # 63C
Cu present	59.30	84.04	69.61	80.48
Zn	37.81	1.452	27.85	0.093
Pb	0.1	8.590	1.00	9.35
Sn	Trace	5.737	1.00	9.03
Sb				0.52
Ni	Trace		0.53	0.32
P				0.145
S				0.060
As				0.023
Fe	1.22		0.004	0.0013
Al	1.15
Mn	0.35
Cu found	59.09	83.64	69.68a	80.54a	aAverage of 3 determinations.
Keywords:	This work is taken in part from the senior independent study of Frederick G  Burton
本文献已被 ScienceDirect 等数据库收录！