A new cryoscopic micro-method for the determination of molecular weights |
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Authors: | W.M. Smit J.H. Ruyter H.F.Van Wijk |
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Affiliation: | Pysisch Chemisch Institut T N O., UtrechtThe Netherlands |
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Abstract: | A method is described for molecular weight determination based on a temperature-heat content curve About 2 mg of substance is required The method is applicable even when solute and solvent form mixed crystals. A wide variety of solvents may be used. The method may yield good results in the polymer field.The accuracy obtained is better than 1%. The new method appears to be more reliable and accurate than known cryobcopic methods |
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