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Extraction of bismuth as iodide with isoamyl acetate and isoamyl alcohol
Authors:HA Mottola  EB Sandell
Institution:School of Chemistry, University of Minnesota, Minneapolis, Minn.U.S.A.
Abstract:The optimum iodide concentration (excess) for the extraction of bismuth as Bil3 into isoamyl acetate from 1—5 N sulfuric acid solution is approximately 5.10-3M. At this iodine concentration the extraction coefficient Bi] isoamyl acetate/Bi]H2O is approximately 130 (25-30°) when the ratio of isoamyl acetate to aqueous phase is 1 : 4. Mixturcs of isoamyl acetate and isoamyl alcohol in the proper ratios extract Bil3 to a greater extent than either solvent alone.
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