1,3-Dihydroxynaphthalene in the Synthesis of Phosphorus-containing Macroheterocycles |
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Authors: | E N Rasadkina P V Slitikov M P Pechkina L K Vasyanina A I Stash E E Nifant'ev |
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Institution: | (1) Moscow State Pedagogical University, Moscow, Russia |
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Abstract: | Original representatives of phosphacyclophanes on the basis of the unsymmetrical 1,3-dihydroxynaphthalene and phosphorous triamides are synthesized by three different procedures, including dismutation. The different procedures are shown to lead to a single structural isomer exclusively. The dismutation reactions of 1,3-dihydroxynaphthalene and resorcinol bisphosphoramidites are compared. Thio and oxo derivatives of phosphacyclophane systems are synthesized. |
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