| N-苯基-3-(p-氯苯)全氢螺[苯并[b]异■唑7,1′环己烷]-4酮的合成及晶体结构 |
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| 引用本文： | 冯亚青,J．Frohlich,F．Sauter,K．Merelier. N-苯基-3-(p-氯苯)全氢螺[苯并[b]异■唑7,1′环己烷]-4酮的合成及晶体结构[J]. 结构化学, 1997, 0(6) |
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| 作者姓名： | 冯亚青 J．Frohlich F．Sauter K．Merelier |
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| 作者单位： | 天津大学应用化学系!天津，300072(冯亚青)，维也纳技术大学有机化学研究所!A－1060，维也纳，奥地利(J．Frohlich，F．Sauter)，维也纳技术大学结晶学矿物学和结构化学研究所!A－1060，维孔纳，奥地利(K．Merelier) |
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| 摘 要： | 合成并测定了N-苯基-3－（p-氯苯）全氢螺[苯并[b]异唑7，1-环已烷]-4-酮（3）的单晶结构，晶体分子式C24H26ClNO2,Mr=395.93，晶体属单科晶系，空间群为P21／c，晶胞参数结构的偏离因子R=0．037，Rw=0．039。分子3存在着两个螺六员环（A和B），A环具有通常的椅式构型，B环是扭船式构型。B环和五员异呼吐环C环并连，C环有些扭曲，结构分析结果表明，分子3具有“顺-顺”构型。
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| 关 键 词： | 螺异■唑化合物 合成 结晶结构 |
Synthesis and Crystal Structure of N-phenyl-3- (p-chlorophenyl )all -hydrospiro (benzo (d ) isoxazole 7, 1 ''''-cyclohexane) -4-one |
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| Y. Feng, J. Frohlich, K. Mereiter, F. Sauter. Synthesis and Crystal Structure of N-phenyl-3- (p-chlorophenyl )all -hydrospiro (benzo (d ) isoxazole 7, 1 ''''-cyclohexane) -4-one[J]. Chinese Journal of Structural Chemistry, 1997, 0(6) |
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| Authors: | Y. Feng J. Frohlich K. Mereiter F. Sauter |
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| Abstract: | N-phenyl- 3- (p-chlorophenyl)-all-hydrospiro (benzo (d ) isoxazole 7, 1 '-cyclohexane ) -4-one 3was synthesized by 1, 3-dipolar cycloaddition of (a)-N-phenyl-a-(4-chloro) phenyl nitrone tospiro [5. 5] undec-1-ene-3-one. The crystal structure of 3, C24H26CINO2, Mr = 395. 93 ) was determined by X-ray diffraction method- The crystal belongs to monoclinic system with spacegroup P21/c, a= 6. 017(1), b= 22. 746(3), c= 15. 035(2) A, g= 1O5. 68(1),final R and R Molecule 3consists of two spiro-sixrings(A and B)to one of which(B) the isoxazoline ring(C) is anuIated.Ring A has the usual chair con formation. Ring B, the second spiro-sixring, shows on the contrary a somewhat twisted boat-like con formation. The result of structure analysis indicates thatMolecule 3 has the ″cis- cis″ conformation. |
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| Keywords: | spiro-isoxazole compound synthesis crystal structure |
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