| Brusselator的化学亲合势及熵产生的振荡 |
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| 引用本文： | 高执棣,李明成,刘君利.Brusselator的化学亲合势及熵产生的振荡[J].物理化学学报,1992,8(6):824-828. |
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| 作者姓名： | 高执棣 李明成 刘君利 |
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| 作者单位： | Department of Chemistry, Peking University, Beijing 100871 |
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| 摘 要： | 迄今为止,化学振荡的研究主要限于描述物质浓度的振荡,有关热力学量的振荡报导极少.这可能是由于振荡机理(或模型)中的热力学量无法确定的缘故.我们采用将标准化学亲合势作为可调参数的方法,并依据非平衡态热力学理论中热力学量与物质的浓度关系,使得热力学量振荡的研究变为现实.本文用计算机数值计算,得出了开放系Brusseltor各元反应的反应速率、化学亲合势及体系熵产生随时间的变化行为,展示了它们的振荡特征。
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| 关 键 词： | 振荡 化学亲合势 熵产生 |
| 收稿时间： | 1991-07-23 |
| 修稿时间： | 1992-07-17 |
THE OSCILLATION OF CHEMICAL AFFINITY AND ENTROPY PRODUCTION OF THE BRUSSELATOR |
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| Gao Zhidi,Li Mingcheng,Liu Junli.THE OSCILLATION OF CHEMICAL AFFINITY AND ENTROPY PRODUCTION OF THE BRUSSELATOR[J].Acta Physico-Chimica Sinica,1992,8(6):824-828. |
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| Authors: | Gao Zhidi Li Mingcheng Liu Junli |
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| Institution: | Department of Chemistry, Peking University, Beijing 100871 |
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| Abstract: | The time variation of chemical affinities A_p and entropy production ? of an open Brusselator system has been studied. It was found that the oscillating characteristics of A_p and ? are quite different. While A_p oscillations with a single peak in every period, ? has either a single peak or two-peak oscillations which depend on the kinetic mechanism of oscillation or values of A_p~?. The meaning to study oscillation of thermodynamic quantities was also discussed. |
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| Keywords: | Oscillation Chemical affinity Entropy production |
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