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不同碳源催化化学气相沉积制备自支撑C/Ni-Fiber复合电极材料的电容脱盐性能
引用本文:王喜文,姜芳婷,索全伶,方玉珠,路勇.不同碳源催化化学气相沉积制备自支撑C/Ni-Fiber复合电极材料的电容脱盐性能[J].物理化学学报,2011,27(11):2605-2612.
作者姓名:王喜文  姜芳婷  索全伶  方玉珠  路勇
作者单位:1. Department of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, P. R. China; 2. Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, Shanghai 200062, P. R. China
基金项目:国家自然科学基金,上海市科委"科技启明星(跟踪)计划"
摘    要:以甲烷、乙烯、乙醇和正丁醇为碳源,通过催化化学气相沉积在具有三维开放网络结构的烧结8μm-Ni金属纤维上沉积碳的方法,制备了以金属Ni纤维网络为集流极、沉积碳为离子存储库的薄层大面积自支撑C/Ni-fiber复合电极材料.用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、热重分析(TGA)、X射线衍射(XRD)、N2-吸脱附等温线和循环伏安与电化学阻抗谱对电极材料进行了表征,并考察了其作为电极的电容脱盐性能.乙烯、甲烷、正丁醇和乙醇为碳源的沉积碳形态分别为鱼骨状碳纳米管(CNTs)、石墨烯面取向与轴平行的CNTs、棒状和蠕虫状碳纳米纤维(CNFs).C/Ni-fiber复合电极材料对NaCl的电吸附容量顺序为:乙烯>正丁醇>甲烷>乙醇,这与复合电极的电化学特性、孔结构和碳的纳米结构相关.在1.2 V的工作电压下,以乙烯为碳源制备的C/Ni-fiber复合电极材料对水溶液中NaCl(100 mg·L-1)的电吸附容量达159μmol·g-1.

关 键 词:碳纳米管  碳纤维  金属纤维  化学气相沉积  自支撑电极  电容脱离子  
收稿时间:2011-05-25
修稿时间:2011-09-05

Self-supporting Macroscopic Carbon/Ni-Fiber Hybrid Electrodes Prepared by Catalytic Chemical Vapor Deposition Using Various Carbonaceous Compounds and Their Capacitive Deionization Performance
WANG Xi-Wen,JIANG Fang-Ting,SUO Quan-Ling,FANG Yu-Zhu,LU Yong.Self-supporting Macroscopic Carbon/Ni-Fiber Hybrid Electrodes Prepared by Catalytic Chemical Vapor Deposition Using Various Carbonaceous Compounds and Their Capacitive Deionization Performance[J].Acta Physico-Chimica Sinica,2011,27(11):2605-2612.
Authors:WANG Xi-Wen  JIANG Fang-Ting  SUO Quan-Ling  FANG Yu-Zhu  LU Yong
Institution:1. Department of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, P. R. China; 2. Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, Shanghai 200062, P. R. China
Abstract:We prepared a series of self-supported macroscopic C/Ni-fiber hybrid electrodes by catalytic chemical vapor deposition(CCVD) using methane,ethylene,ethanol and n-butanol as carbon sources to embed carbon onto a three-dimensional network of sinter-locked conductive 8μm-nickel fibers.For the as-prepared hybrid electrodes,the Ni-microfibrous network serves as a current collector and the carbons as ion storage media while the macroporous void space serves as an electrolyte reservoir.We characterized the hybrid electrodes using scanning electron microscopy(SEM),transmission electron microscopy(TEM),thermogravimetric analysis(TGA),X-ray diffraction(XRD),N2 isothermal adsorption-desorption, cyclic voltammetry and electrochemical impedance spectroscopy.The desalination performance of the C/Ni-fiber hybrids was evaluated as electrodes in a capacitive deionization system.The carbon morphology is dependent on the carbonaceous compounds used in CCVD:carbon nanotubes (CNTs) with fishbone-like structure,CNTs with inclined graphene layers parallel to the tube axis,rod-like carbon nanofibers(CNFs) and worm-like CNFs for ethylene,methane,n-butanol and ethanol.The desalination performance of these hybrid electrodes with respect to the carbonaceous compounds decreases as follows:ethylene>n-butanol>methane>ethanol,which correlates with their electrochemical features,pore structures and their carbon nanostructures.The hybrid electrodes obtained using ethylene as the carbon source gave a maximum eiectrosorption capacity of 159μmol·g-1 using a direct current voltage of 1.2 V and a 100 mg·L-1 NaCI aqueous solution as raw water.
Keywords:Carbon nanotube  Carbon fiber  Metal fiber  Chemical vapor deposition  Self-supporting electrode  Capacitive deionization  
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