Studies of the compositions of Pd(II) hydrolysis products |
| |
| Authors: | S Yu Troitskii M A Fedotov V A Likholobov |
| |
| Institution: | (1) Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Akademika Lavrent'eva, 630090 Novosibirsk, Russian Federation |
| |
| Abstract: | The characterization of the clusters formed on alkaline hydrolysis of PdCl4]2– was performed using17O,23Na,35Cl,133Cs NMR and UV spectroscopy. The chemical composition of the clusters was found to be Pd(OH)2]
n
·nNaCl. No mononuclear oxo- or hydroxocomplexes were detected. The spatial structure of the clusters is stabilized by alkali metal cations.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 675–679, April, 1993. |
| |
| Keywords: | palladium(II) hydrolysis polynuclear complexes NMR UV spectroscopy |
| 本文献已被 SpringerLink 等数据库收录！ |
|
