Catalytic phosphorylation of polyfluoroalkanols. 11. α-Polyfluoroalkylbenzyldichlorophosphates as phosphorylating agents in the catalytic phosphorylation of primary polyfluoroalkanols

Conclusions -Polyfluoroalkylbenzyldichlorophosphates react, in the presence of catalytic quantities of certain metals or their salts, with polyfluorinated primary alcohols with the formation of phosphorylation products [bis(polyfluoroalkyl)(-polyfluoroalkylbenzyl)phosphates] exclusively.For previous communication, see [1].Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1660–1664, July, 1989.