| 三甲基硅氧基钠参与下的氟烷基碘与烯烃反应 |
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| 引用本文： | 陈庆云,吴建平. 三甲基硅氧基钠参与下的氟烷基碘与烯烃反应[J]. 有机化学, 1990, 10(3): 274-277 |
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| 作者姓名： | 陈庆云 吴建平 |
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| 作者单位： | 中国科学院上海有机化学研究所，中国科学院上海有机化学研究所 上海，200032，上海，200032 |
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| 摘 要： | 近年来,氟烷基碘(1)对烯烃的加成反应得到了广泛的研究。我们已经报道了铜、锌、镁、铁、镍、钯、铂、铱等金属催化下的反应,以及cd型阴离子引发下的加成反
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| 关 键 词： | 氟烷基碘 烯烃 加成反应 |
Reaction of Fluoroalkyl Iodides with Olefines in Sodium Trimethylsilyl Oxide |
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| CHEN Qing-yun,WU Jian-Ping. Reaction of Fluoroalkyl Iodides with Olefines in Sodium Trimethylsilyl Oxide[J]. Chinese Journal of Organic Chemistry, 1990, 10(3): 274-277 |
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| Authors: | CHEN Qing-yun WU Jian-Ping |
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| Affiliation: | CHEN Qing-yun,WU Jian-Ping, shanghai Institute of Organia Chemistry Academia Sinica,200032 Shanghai |
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| Abstract: | The addition reactions of fiuoroalkyl iodides(1) with olefines in a system of hex-methyldisiloxane and sodium methoxide was investigated. The reaction afforded fluoroalkyllefines(2) in good yields. Addition of p-dinitrobenzene or hydroquinone depressed the reac-ion significantly. Allyl ether reacted with R_fI in this system to give tetrahydrofuran de-ivatives. All the results indicate that an electron transfer process might be involved. |
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| Keywords: | trimethylsilyl oxideanion addition reaction sing electron transfer reaction |
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