Zwitterionic pi-radical involving EDT-TTF-imidazole and F4TCNQ: redox properties and self-assembled structure by hydrogen-bonds and multiple S...S interactions |
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Authors: | Murata Tsuyoshi Morita Yasushi Yakiyama Yumi Nishimura Yoshie Ise Tomoaki Shiomi Daisuke Sato Kazunobu Takui Takeji Nakasuji Kazuhiro |
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Institution: | Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka, 560-0043, Japan. |
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Abstract: | The reaction between an imidazole-functionalized EDT-TTF and F(4)TCNQ produced a zwitterionic pi-radical, which formed a self-assembled structure by the cooperation of hydrogen-bonds and multiple S...S interactions and exhibited three-step oxidation processes and a high electrical conductivity as a single-component organic molecule. |
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