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Zwitterionic pi-radical involving EDT-TTF-imidazole and F4TCNQ: redox properties and self-assembled structure by hydrogen-bonds and multiple S...S interactions
Authors:Murata Tsuyoshi  Morita Yasushi  Yakiyama Yumi  Nishimura Yoshie  Ise Tomoaki  Shiomi Daisuke  Sato Kazunobu  Takui Takeji  Nakasuji Kazuhiro
Institution:Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka, 560-0043, Japan.
Abstract:The reaction between an imidazole-functionalized EDT-TTF and F(4)TCNQ produced a zwitterionic pi-radical, which formed a self-assembled structure by the cooperation of hydrogen-bonds and multiple S...S interactions and exhibited three-step oxidation processes and a high electrical conductivity as a single-component organic molecule.
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