Synthesis and Crystal Structure of 3,3'-Bis(5-(N-(4-hydroxylphenyl)imidomethyl)- pyrrol-2-yl)pentane·2CH_3OH |
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引用本文: | 徐兰,刘尚远,尹振明.Synthesis and Crystal Structure of 3,3'-Bis(5-(N-(4-hydroxylphenyl)imidomethyl)- pyrrol-2-yl)pentane·2CH_3OH[J].结构化学,2010,29(4):613-617. |
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作者姓名: | 徐兰 刘尚远 尹振明 |
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作者单位: | College;Chemistry;Life;Science;Tianjin;Laboratory;Cytogenetics;Molecular;Regulation;Normal;University; |
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基金项目: | supported by the National Natural Science Foundation of China (No. 20702038) |
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摘 要: | 3,3'-Bis(5-(N-(4-hydroxylphenyl)imidomethyl)pyrrol-2-yl)pentane 1 has been synthesized and characterized. The crystal of its methanol complex, 1·(CH3OH)2, belongs to the orthorhombic system, space group Pccn with a = 18.094(2), b = 11.6890(16), c = 13.3629(19) , V = 2826.3(7) 3, Z = 8, C14.5H18N2O2, Mr = 252.31, Dc = 1.186 g/cm3, F(000) = 1080 and μ(MoKα) = 0.080 mm-1. The final R = 0.0662 and wR = 0.1801 for 1908 observed reflections with I 2σ(I), and R = 0.0800 and wR = 0.1948 for all reflections. In the solid state, bridged by included methanol molecules, the molecules of compound 1 form interpenetrated grid structure through N–H···O and O–H···O hydrogen bonds.
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关 键 词: | 羟基苯基 网格结构 晶体 合成 吡咯 戊烷 甲醇分子 正交晶系 |
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