| 关于O-烷基硫代磷酰二氯重排反应的讨论 |
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| 引用本文： | 张景龄,胡水生.关于O-烷基硫代磷酰二氯重排反应的讨论[J].高等学校化学学报,1983,4(3):329. |
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| 作者姓名： | 张景龄 胡水生 |
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| 作者单位： | 华中师范学院化学系 |
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| 摘 要： | 本文用气相色谱研究了O-烷基硫代磷酰二氯的重排反应。提出了重排反应的机理,并运用软硬酸碱理论进行了讨论。第一次用重排转位的方法制得了S-异丙基硫代磷酰二氯。
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| 收稿时间： | 1982-01-03 |
A DISCUSSION ABOUT THIONO-THIOLO REARRANGEMENT OF O-ALKYL PHOSPHORO- DICHLORIDOTHIOATES |
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| Zhang Jingling,Hu Shuisheng.A DISCUSSION ABOUT THIONO-THIOLO REARRANGEMENT OF O-ALKYL PHOSPHORO- DICHLORIDOTHIOATES[J].Chemical Research In Chinese Universities,1983,4(3):329. |
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| Authors: | Zhang Jingling Hu Shuisheng |
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| Institution: | Department of Chemistry, Central China Normal University, Wuhan |
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| Abstract: | The results of using gas chromatography to follow the reactions revealed that four different reactions were existed simultaneously in the isomerization of O-alkyl phosphorodichloridothioates. They were considered as a combination of rearrangement, decomposition and disproportion reaction as well as hydrolysis. The reaction mechanism was preliminarily discussed according to HSABtheory. It was the first time that S-isopropyl phosphorodichloridothioate was synthesized by using the isomerization method. |
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