Some Diels-Alder reactions with 4-vinyl isoquinoline derivatives |
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Authors: | S. F. Dyke M. Sainsbury D. W. Brown R. D. J. Clipperton |
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Affiliation: | School of Chemistry and Chemical Engineering, Bath University of Technology, Bath BA2 7AY, Somerset, England |
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Abstract: | The first preparation of 4-vinylisoquinoline derivatives is described. 1,4-Cycloadducts have been obtained by their interaction with the dienophiles maleic anhydride, acrylic acid, p-benzoquinone, propriolic acid and benzyne. The structures of the adducts have been assigned on the basis of chemical, but mainly spectroscopic evidence. |
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