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Electrochemical studies of bi- and polymetallic complexes featuring acetylide based bridging ligands |
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| Authors: | Paul J Low Rachel L Roberts Richard L Cordiner František Hartl | ||
| Institution: | (1) Department of Chemistry, University of Durham, South Rd, Durham, DH1 3LE, UK;(2) Van’t Hoff Institute for Molecular Sciences, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands | ||
| Abstract: | Acetylide-based bridging ligands have been widely used in the preparation of complexes that display a degree of electronic
interaction between metal-based redox groups located at the ligand termini. The electrochemical response of these systems
has been selectively reviewed, with a focus on the variation in properties that accompany changes in the structure of the
bridging ligand and the nature of the metal groups.
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| Keywords: | Acetylide Metal complex Mixed-valence chemistry | ||
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