Suzuki-Miyaura cross-coupling of benzylic carbonates with arylboronic acids |
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| Authors: | Kuwano Ryoichi Yokogi Masashi |
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| Institution: | Department of Chemistry, Graduate School of Siences, Kyushu University, 6-10-1 Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan. rkuwascc@mbox.nc.kyushu-u.ac.jp |
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| Abstract: | The cross-coupling of benzylic carbonates with arylboronic acids gave the corresponding diarylmethanes in high yields by use of the palladium catalyst generated in situ from Pd(eta(3)-C(3)H(5))Cl](2) and 1,5-bis(diphenylphosphino)pentane (DPPPent). The Suzuki-Miyaura reaction using DPPPent-palladium catalyst is applicable to syntheses of a broad range of functionalized diarylmethanes. reaction: see text] |
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