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Mechanism of grignard reagent formation. Further evidence for the surface nature of the reaction |
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| Authors: | Janusz Rachon H. M. Walborsky |
| Affiliation: | Department of Chemistry, Florida State University, Tallahassee, FL 32306 USA |
| Abstract: | The use of Rieke magnesium permits one to obtain reaction with (S)-(+)-1-bromo-1-methyl-2,2-diphenylcyclopropane (1) at −65°C to yield a chiral Grignard reagent that is 33–43% optically pure. |
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