Alkylation of pyridinecarbaldehyde oximes with epoxy compounds |
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Authors: | N Şen Y Kar S Kurbanov |
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Institution: | (1) Department of Chemistry, University of Selcuk, 42031 Konya, Turkey;(2) Department of Chemical Engineering, University of Selcuk, 42031 Konya, Turkey |
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Abstract: | O-and N-Alkylation products were obtained by reactions of pyridine-2-,-3-, and-4-carbaldehyde oximes with enantiomerically
pure and racemic epoxy compounds (1,2-epoxypropane, 1-phenyl-1,2-epoxyethane, 1-chloro-2,3-epoxypropane, and 1-bromo-2,3-epoxypropane)
in the presence of bases and under conditions of phase-transfer catalysis. A series of new amino alcohols was synthesized
by condensation of amines with products of O-alkylation of pyridinecarbaldehyde oximes with 1-halo-2,3-epoxypropanes.
Published in Russian in Zhurnal Organicheskoi Khimii, 2007, Vol. 43, No. 3, pp. 450–454.
The text was submitted by the authors in English. |
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