An unusual 3D entangled Co(II) coordination polymer directed by ferromagnetic molecular building block |
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| Authors: | Liu Jian-Qiang Liu Bin Wang Yao-Yu Liu Ping Yang Guo-Ping Liu Rui-Ting Shi Qi-Zhen Batten Stuart R |
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| Institution: | Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University, Xi'an 710069, P. R. China. |
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| Abstract: | A fascinating 3D entangled metal-organic framework, namely, {Co(2)(bcp)(2)]·3H(2)O}(n) (1), was obtained through the solvothermal generation of flexible and long dicarboxylate (bcp) and metal salt. The crystal structure contains a 1D metal chain with bcp ligands wrapped around it in a wavy line and features an unusual entangled topological net. Furthermore, the magnetic behavior of 1 was also studied and indicated the existence of ferromagnetic interaction and long-range ordering character. |
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