| 六氯化铈三烷基鏻的合成 |
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| 引用本文： | 沈琪,周朋,宋丕莹. 六氯化铈三烷基鏻的合成[J]. 应用化学, 1984, 0(4): 50-54 |
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| 作者姓名： | 沈琪 周朋 宋丕莹 |
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| 作者单位： | 中国科学院长春应用化学研究所 |
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| 摘 要： | 合成了三个新的(HPR3)2CeCl6络合物,其中R=C2H5,C3H7,C4H9。络合物经元素分析,红外和紫外光谱鉴定。用热重分析法研究了这些络合物的热分解行为,结果表明,它们于分解温度时,都首先失去一个氯原子。
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| 收稿时间： | 1984-03-30 |
| 修稿时间： | 1984-06-15 |
PREPARATION OF HEXACHLOROCERIUM-TRIALKYLPHOSPHONIUM |
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| Shen Qi,Zhou Peng,Song Piying. PREPARATION OF HEXACHLOROCERIUM-TRIALKYLPHOSPHONIUM[J]. Chinese Journal of Applied Chemistry, 1984, 0(4): 50-54 |
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| Authors: | Shen Qi Zhou Peng Song Piying |
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| Affiliation: | Changchun Institute of Applied Chemistry, Academia Sinica |
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| Abstract: | Three new complexes (HPR3)2CeCl6. where R=-C2H5-C3H7,-C4C9,were synthesized by means of adding PR3 into H2CeCl6 ethanol solution under bubbling of dry HCl. The complexes were identified by elemental analysis, IR and visible spectra. In the thermogram of the complexes an initial mass loss corresponding to the loss of a chlorine atom is observed. |
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