| 可逆加成-断裂链转移自由基聚合研究进展 |
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| 引用本文： | 游倩倩,张普玉,张怀敏,庄玉伟.可逆加成-断裂链转移自由基聚合研究进展[J].化学研究,2012(2):94-99. |
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| 作者姓名： | 游倩倩 张普玉 张怀敏 庄玉伟 |
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| 作者单位： | [1]河南大学化学化工学院,河南开封475004 [2]河南省科学院高新技术研究中心,河南郑州450002 |
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| 基金项目： | 河南省教育厅基金资助项目（2009A150006） |
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| 摘 要： | 综述了活性/可控自由基聚合中的可逆加成-断裂链转移(RAFT)自由基聚合研究进展;总结了RAFT试剂、RAFT聚合反应条件、RAFT聚合物及其结构形貌的最新研究进展;指出RAFT自由基聚合反应已被作为重要方法之一用于合成具有特定分子结构的聚合物.
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| 关 键 词： | 可逆加成-断裂链转移 自由基聚合 研究进展 |
Research progress in reversible addition-fragmentation chain transfer radical polymerization |
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| YOU Qian-qian,ZHANG Pu-yu,ZHANG Huai-min,ZHUANG Yu-wei.Research progress in reversible addition-fragmentation chain transfer radical polymerization[J].Chemical Research,2012(2):94-99. |
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| Authors: | YOU Qian-qian ZHANG Pu-yu ZHANG Huai-min ZHUANG Yu-wei |
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| Institution: | 1.College of Chemistry and Chemical Engineering,Henan University,Kaifeng 475004,Henan,China; 2.High ＆ New Technology Research Center,Henan Academy of Science,Zhengzhou 450002,Henan,China) |
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| Abstract: | A review is provided of the recent progress in reversible addition-fragmentation chain transfer（RAFT） radical polymerization,where RAFT agent,RAFT polymerization reaction condition,and RAFT polymerized products as well as their microstructure and morphology are highlighted.It is pointed out that RAFT radical polymerization has been adopted as an important method to synthesize polymers with specifically designed molecular structure. |
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| Keywords: | chain transfer agent radical polymerization research progress |
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