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CeO_2/ZnO复合纳米管的制备及其光催化性能的研究
引用本文:李长全,罗来涛,熊光伟.CeO_2/ZnO复合纳米管的制备及其光催化性能的研究[J].化学学报,2010,68(10):1023-1026.
作者姓名:李长全  罗来涛  熊光伟
作者单位:1. 南昌航空大学分析测试中心,南昌,330063
2. 南昌大学应用化学研究所,南昌,330031
基金项目:江西教育厅科研基金(GJJ08021);高等学校博士学科点专项研究基金(20040403001)
摘    要:用纳米CeO2掺入ZnO纳米管制备了CeO2/ZnO复合纳米管,考察了复合纳米管的光学及其光催化性能,并运用X射线衍射、透射电镜、比表面积测定和紫外-可见漫反射光谱等技术对样品进行了表征.结果表明,与ZnO纳米管相比,CeO2/ZnO复合纳米管的比表面积虽有所降低,但光催化活性有所提高,随着复合纳米CeO2量的增加,催化剂的光催化活性相应降低,太阳光下CeO2/ZnO复合纳米管对甲基橙溶液也有较高的催化活性.

关 键 词:CeO2/ZnO  复合纳米管  制备  光催化
收稿时间:2009-09-09
修稿时间:2009-11-18

Study of the Preparation and Photocatalysis Performance of CeO2/ZnO Mixed Nanometer Tubes
Li,Changquan,Luo,Laitao,Xiong,Guangwei.Study of the Preparation and Photocatalysis Performance of CeO2/ZnO Mixed Nanometer Tubes[J].Acta Chimica Sinica,2010,68(10):1023-1026.
Authors:Li  Changquan  Luo  Laitao  Xiong  Guangwei
Institution:(Center of Analysis And Testing of Nanchang Hangkong University, Nanchang 330063)
(Institute of Applied Chemistry, Nanchang University, Nanchang 330031)
Abstract:CeO2/ZnO mixed nano-tubes were prepared by doping nano-CeO2 into ZnO nano-tubes. The properties of optics and photo-catalysis of CeO2/ZnO mixed nano-tubes were studied, and the samples were characterized by means of X-ray diffraction, transmission electron microscopy, specific surface area determination and ultraviolet-visual diffuse reflection spectroscopy. The result showed that the specific surface of CeO2/ZnO mixed nano-tubes decreased, but the degradation rate of CeO2/ZnO mixed nano-tubes for methyl orange was higher than that of ZnO nano-tubes. With the increase of content of CeO2 in CeO2/ZnO mixed nano-tubes, the degradation rate of methyl orange decreased accordingly. CeO2/ZnO mixed nano-tubes had certain degradation ability for methyl orange under sunlight.
Keywords:CeO2/ZnO  mixed nano-tubes  preparation  photo-catalysis
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