The palladium(II)-catalyzed Nazarov reaction |
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Authors: | Bee Cisco Leclerc Eric Tius Marcus A |
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Affiliation: | Department of Chemistry, 2545 The Mall, University of Hawaii, Honolulu, HI 96822, USA. |
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Abstract: | The PdCl(2)-catalyzed cyclization of alpha-alkoxy dienones leads to 2-hydroxycyclopentenones, whereas the Pd(OAc)(2)-catalyzed reaction leads to cross-conjugated cyclopentenones through an oxidative process. [reaction: see text] |
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