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Self-assembly of a unique hexadecanuclear [4 x (2 x 2)]-Pb16 'grid of grids' type structure
Authors:Onions Stuart T  Frankin Anthony M  Horton Peter N  Hursthouse Michael B  Matthews Craig J
Affiliation:Division of Chemistry, School of Science, Nottingham Trent University, Clifton Lane, Nottingham, UK NG11 8NS.
Abstract:A new ligand containing a linear sequence of four-tridentate chelating subunits built around alkoxide and pyrimidine bridging groups undergoes a spontaneous self-assembly process with Pb(CF3SO3)2 to produce a unique hexadecanuclear [4 x (2 x 2)] 'grid of grids' type structure with external dimensions of 26 A.
Keywords:
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