Self-assembly of a unique hexadecanuclear [4 x (2 x 2)]-Pb16 'grid of grids' type structure |
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Authors: | Onions Stuart T Frankin Anthony M Horton Peter N Hursthouse Michael B Matthews Craig J |
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Affiliation: | Division of Chemistry, School of Science, Nottingham Trent University, Clifton Lane, Nottingham, UK NG11 8NS. |
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Abstract: | A new ligand containing a linear sequence of four-tridentate chelating subunits built around alkoxide and pyrimidine bridging groups undergoes a spontaneous self-assembly process with Pb(CF3SO3)2 to produce a unique hexadecanuclear [4 x (2 x 2)] 'grid of grids' type structure with external dimensions of 26 A. |
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