ZnO纳米线负载Pd1单原子催化剂催化若干反应性能的考察

将孤立的Pd原子分散到ZnO纳米线(NWs)上作为单原子催化剂(SACs),并考察了它们在若干反应中的催化性能.Pd1/ZnO SAC对甲醇蒸汽重整制氢反应表现出高的活性、稳定性和CO2选择性.该催化剂体系对CO和H2的氧化也具有高活性,但在富氢物料中CO优先氧化反应中的催化剂性能较差,这主要是由于在ZnO负载的Pd1原子上H2氧化的强竞争反应所致.常压下在Pd1/ZnO SAC上就可发生逆水汽变换反应.该系列催化反应测试结果清楚地表明,选择合适金属与载体对开发分子催化转化用单原子催化剂至关重要.

Probing the catalytic behavior of ZnO nanowire supported Pd1 single-atom catalyst for selected reactions

We have dispersed individual Pd atoms onto ZnO nanowires (NWs) as single-atom catalysts (SACs) and evaluated their catalytic performance for several selected catalytic reactions. The Pd1/ZnO SAC is highly active, stable, and selective towards CO2 for steam reforming of methanol to produce hy-drogen. This catalyst system is active for oxidation of CO and H2 but performs poorly for preferential oxidation of CO in hydrogen-rich stream primarily due to the strong competitive oxidation of H2 on ZnO supported Pd1 atoms. At ambient pressure, reverse water-gas-shift reaction occurs on the Pd1/ZnO SAC. This series of tests of catalytic reactions clearly demonstrate the importance of se-lecting the appropriate metal and support to develop SACs for catalytic transformation of molecules.