| 高效固体酸SBA-15-Zr(OTf)3催化胺或醇开环环氧化合物 |
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| 引用本文： | Kamlesh N.Tayade,王连月,尚森森,戴文,Manish Mishra,高爽.高效固体酸SBA-15-Zr(OTf)3催化胺或醇开环环氧化合物[J].催化学报,2017,38(4). |
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| 作者姓名： | Kamlesh N.Tayade 王连月 尚森森 戴文 Manish Mishra 高爽 |
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| 作者单位： | 1. 中国科学院大连化学物理研究所洁净能源国家实验室,辽宁大连,116023;2. 德赛大学技术学院化学工程系,Shah-Schulman表面科学与纳米技术中心,古吉拉特邦,纳迪亚德市,印度 |
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| 基金项目： | the CAS President's International Fellowship Initiative，the National Natural Science Foundation of China (21273225 and 21403219).中国科学院国际人才计划，国家自然科学基金 |
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| 摘 要： | 通过简单的一锅两步法制备了三氟金属(铝,钛,锆)接枝介孔SBA-15 (AlTf/S,TiTf/S,ZrTf/S)固体酸材料,并通过XRD,N2吸附,TGA,FTIR,原位吡啶FTIR和元素分析对这些材料进行了详细的表征.其中,ZrTf/S能够高效催化环氧化物温和条件下被胺或醇开环生成对应β-氨基醇或β-烷氧基醇,并且催化剂能循环利用.ZrTf/S相较于AlTf/S和TiTf/S酸性最强,因而催化活性也最高.
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| 关 键 词： | 环氧开环 酸催化 三氟金属 接枝催化剂 介孔硅 |
Zirconium triflate grafted on SBA-15 as a highly efficient solid acid catalyst for ring opening of epoxides by amines and alcohols |
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| Kamlesh N.Tayade,Lianyue Wang,Sensen Shang,Wen Dai,Manish Mishra,Shuang Gao.Zirconium triflate grafted on SBA-15 as a highly efficient solid acid catalyst for ring opening of epoxides by amines and alcohols[J].Chinese Journal of Catalysis,2017,38(4). |
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| Authors: | Kamlesh NTayade Lianyue Wang Sensen Shang Wen Dai Manish Mishra Shuang Gao |
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| Abstract: | Metal (Al,Ti,Zr) triflate grafted mesoporous SBA-15 (AlTf/S,TiTf/S,ZrTf/S) samples were synthesized as inexpensive solid acid materials by a simple one-pot-two-step synthesis methodology.These materials were characterized by X-ray diffraction,N2-sorption,thermogravimetric analysis,Fourier transform infrared spectroscopy (FT-IR),in-situ pyridine FT-IR spectroscopy,and elemental analysis.ZrTf/S was found to be a highly efficient and reusable solid acid catalyst for ring opening of epoxides with amines and alcohols and produced β-amino alcohols and β-alkoxy alcohols respectively under ambient reaction conditions.The ZrTf/S catalyst showed the highest activity,which was attributed to its high acidity compared with that of the Ti and Al containing samples. |
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| Keywords: | Epoxide ring opening Acid catalysis Metal triflate Grafted catalyst Mesoporous silica |
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